» March 2005: Aniston files for divorce, citing "irreconcilable differences." » April 2005: Paparazzi photos of Pitt, Jolie and her adopted son Maddox on a beach in Kenya surface, seeming to confirm long-standing rumors that the pair are a romantic item.» July 2005: Pitt and Jolie pose for a photo shoot for W magazine entitled "Domestic Bliss," portraying them as a family with several children.In the new issue of Rolling Stone magazine, Pitt reiterates Jolie's recent confession that they fell in love while making the movie.After being asked why the action film is his favourite film, he explained: 'Because you know... Because I fell in love.' Complicated: Brad Pitt admitted he 'fell in love' with Angelina Jolie on the 2004 set of Mr & Mrs Smith - while he was still married to Jennifer Aniston Pitt's revelation comes two months after Jolie told the New York Times that she fell for him while making the movie.We just became kind of a pair." While Jolie adamantly insisted she and Pitt were not seeking to pair up, the pouty-lipped bombshell confessed they were tempted to make more of what they had.
Rumors of an engagement began to swirl when Jolie was spotted at a private viewing at the Los Angeles County Museum of Art's Chinese galleries on Wednesday rocking quite a sparkler on her ring finger.
"And so we were both living, I suppose, very full lives." Click here for more news on Brad Pitt. Jolie said she was committed to life as a single mom when she was paired with Pitt in the espionage action flick. "I, like most people, had a very distant impression of him from ... "I think we were the last two people who were looking for a relationship. "I was quite content to be a single mom." The "Tomb Raider" babe admitted she was thrilled working with Pitt every day while shooting "Smith" in 20.
"Because of the film, we ended up being brought together to do all these crazy things, and I think we found this strange friendship and partnership that kind of just suddenly happened.
» Summer 2004: Pitt and Jolie meet on the set of "Mr. Smith." Rumors of an on-set romance begin almost immediately, though both deny the allegations, saying they are just friends.
» January 2005: Pitt and then-wife Jennifer Aniston announce that they have decided to formally separate after nearly five years of marriage and more than seven years together.